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An Introduction to Organometallic Chemistry by A.W. Parkins PDF

By A.W. Parkins

ISBN-10: 0333364333

ISBN-13: 9780333364338

ISBN-10: 1349181986

ISBN-13: 9781349181988

This publication provides an built-in view of the organometallic chemistry of transition and non-transition parts. Early chapters care for the elemental ideas, guidance and constitution of organometallic compounds. next chapters talk about the reactivity of those compounds and the purposes of organometallic compounds as stoichiometric reagents and catalysts. The textual content is comprehensively referenced all through and is usually a consultant to organometallic literature, expanding its usefulness to all these interested in the examine or educating of this more and more very important department of undergraduate chemistry.

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Extra info for An Introduction to Organometallic Chemistry

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1982). Acc. chem. Res. 15,306 Birchall, J. , Haszeldine, R. , and Wakalski, W. W. (1967). J. chem. Soc. (C) 47 Blackborow, J. , and Young, D. (1979). Metal Vapour Synthesis in Organometallic Chemistry. , and Wilke, G. (1966). Annalen 699,1 Bruce, M. I. (1977). Angew Chem. into Edn Engl. 16, 73 Buiten, E. J. (1975). J. organomet. Chem. , Vallarin"o, L. , and Venanzi, L. M. (1957). J. chem. Soc. 3413 Chock, P. , and Paulik, F. E. /norg. Synth. 14,90 Collman, J. , and Roper, W. R. (1968). Adv. organomet.

27) in that a single regioisomer is produced. 88). 88) Where aqueous conditions are undesirable, it is possible to carry out the diazotisation in absolute ethanol using amyl nitrite and dry hydrogen chloride. The complex salt, ArN 2 AsCI 4 , obtained by addition of arsenic trichloride is subsequently decomposed by the addition of copper powder. 89). 89) The corresponding aryl-antimony and -bismuth compounds can be made similarly. In this method of preparing Group V compounds, the metal becomes oxidised from the tri- to the penta-valent state.

60). , 1976). 62). 62) This reaction is also called an insertion and is most widely used for main group metal compounds. 63). 2 29 PREPARATION OF ORGANOMETALLIC COMPOUNDS \ / 'c=c""--. 63) / \ There are a few examples of 1T-complex formation, such as that occurring between silver nitrate and an alkene, as in equation (2_64) (Quinn and Tsai, 1969) in which the incoming alkene does not, apparently, displace a ligand. 64) NO,Ag '-$-AgNO, However, the interaction between the Ag+ and N03" ions in the starting material (Lindley and Woodward, 1966) is substantially modified by the introduction of the alkene group and this modification can be regarded as a displacement.

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An Introduction to Organometallic Chemistry by A.W. Parkins


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